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Beilstein J. Org. Chem. 2013, 9, 710–716, doi:10.3762/bjoc.9.81
Graphical Abstract
Scheme 1: Synthesis of substrates 1a–c.
Scheme 2: Synthesis of substrates 5a, 5c, 6a and 6c.
Scheme 3: Cyclization of substrate 5a and 5c.
Scheme 4: Proposed mechanism involving π-allylnickel formation.
Scheme 5: Cyclization of substrate 6a and 6c.
Scheme 6: Synthesis and carbometalations of 13.